Photoelectric Effect — Potassium under Violet Light (Worked Example)
Light of wavelength 400 nm strikes a potassium surface with work function Φ = 2.29 eV. What is the maximum kinetic energy of the emitted electrons?
Given
λ = 400 nm
Φ = 2.29 eV
hc = 1240 eV·nm
Find
KE_max of photoelectrons.
Principle
Einstein's photoelectric equation: each photon gives its energy hf to one electron; the leftover after escaping the metal is kinetic energy.
Formula
Solution
Photon energy:
Subtract the work function:
Result:
Unit check
eV − eV = eV — energy units throughout.
What this means physically
Each electron escapes with 0.81 eV — slow by particle standards (about 5.3×10⁵ m/s), but the current flows. Brighter light would eject more electrons, not faster ones; only shorter wavelength raises this energy.
Thinking brighter light makes faster electrons. Intensity controls the number of photons (more electrons); frequency/wavelength alone controls each electron's energy.