Photoelectric Effect — Potassium (Worked Example)
Problem
Blue light of wavelength 450 nm falls on potassium with work function 2.3 eV. Find the maximum kinetic energy of emitted electrons.
Given
λ = 450 nm = 4.50 × 10⁻⁷ m
Φ = 2.3 eV
Find
KE_max.
Principle
KE = hc/λ − Φ — same equation, new metal.
Formula
KE = hc/λ − Φ
Solution
Photon energy:
In eV:
Subtract:
0.46 eV
Unit check
Energy units throughout — correct.
What this means physically
0.46 eV — the electron crawls out. Note red light (700 nm, 1.77 eV) could never eject from potassium no matter how bright — below Φ, zero emission. Frequency, not intensity, rules.
Common mistake
Thinking brighter light gives faster electrons. Brightness adds photons (more electrons); only shorter wavelength adds energy per electron.